Notice: Undefined index: inline in /home/www/hosts/www.ourexperiment.org/docs/export/xml.php on line 68

Notice: Undefined index: inline in /home/www/hosts/www.ourexperiment.org/docs/export/xml.php on line 68
68896927Hydrolysis of KAB8-17 (to give KAB119-1)
Experiments
plus.google.com-+KatrinaBadiolaKatrina Badiola [b][u]Hazard and Risk Assessment[/u][/b] [data]5317[/data] [b][u]Procedure[/u][/b] [b]28/01/14.[/b] Suspended KAB8-17 in ethanol and HCl (1 M). Heated to reflux from 1500; oil bath approx. 130 ° C. Yellowish heterogenous solution. [b]29/01/14.[/b] 0800, clear mixture homogenous and orange. Allowed to cool. Basified to pH 11-13 using solid KOH (about 4 g). Extracted with dichloromethane (2 × 100 mL) and ethyl acetate (100 mL). Combined organic fractions were dried with Na2SO4, concetrated under reduced pressure and dried in vacuo to give an orange solid (1.49 g, 87%) HNMR consistent with the expected product. No purification required. [data]5319[/data][data]5317[/data] --------------------------------------------]]>
START: 28/01/14
FINISH: 31/01/14

Scheme


Hazard and Risk Assessment
HNMR KAB119-1 300 MHz CDCl3


Procedure
28/01/14. Suspended KAB8-17 in ethanol and HCl (1 M). Heated to reflux from 1500; oil bath approx. 130 ° C. Yellowish heterogenous solution.

29/01/14. 0800, clear mixture homogenous and orange. Allowed to cool. Basified to pH 11-13 using solid KOH (about 4 g). Extracted with dichloromethane (2 × 100 mL) and ethyl acetate (100 mL). Combined organic fractions were dried with Na2SO4, concetrated under reduced pressure and dried in vacuo to give an orange solid (1.49 g, 87%)

HNMR consistent with the expected product. No purification required.

Raw HNMR KAB119-1 300 MHz CDCl3
HNMR KAB119-1 300 MHz CDCl3


--------------------------------------------
Linked Posts
]]>2014-01-28T22:28:32+00:002014-02-20T23:17:21+00:009248278731c95b7376b4cb3e72da657a1https://www.ourexperiment.org/data/5301.xmlhttps://www.ourexperiment.org/data/5317.xmlhttps://www.ourexperiment.org/data/5319.xmlhttps://www.ourexperiment.org/data/5321.xmlhttp://www.ourexperiment.org/uri/2c4https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.htmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.htmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.pnghttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6889https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6894https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6895https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6896https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6897https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6906https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6924https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6925https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6926https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6927https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=7055
68897055Hydrolysis of KAB8-17 (to give KAB119-1)
Experiments
plus.google.com-+KatrinaBadiolaKatrina Badiola [b][u]Hazard and Risk Assessment[/u][/b] [data]5317[/data] [b][u]Procedure[/u][/b] [b]28/01/14.[/b] Suspended KAB8-17 in ethanol and HCl (1 M). Heated to reflux from 1500; oil bath approx. 130 ° C. Yellowish heterogenous solution. [b]29/01/14.[/b] 0800, clear mixture homogenous and orange. Allowed to cool. Basified to pH 11-13 using solid KOH (about 4 g). Extracted with dichloromethane (2 × 100 mL) and ethyl acetate (100 mL). Combined organic fractions were dried with Na2SO4, concetrated under reduced pressure and dried in vacuo to give an orange solid (1.49 g, 87%) HNMR consistent with the expected product. No purification required. [data]5319[/data][data]5317[/data] --------------------------------------------]]>
START: 28/01/14
FINISH: 31/01/14

Scheme


Hazard and Risk Assessment
HNMR KAB119-1 300 MHz CDCl3


Procedure
28/01/14. Suspended KAB8-17 in ethanol and HCl (1 M). Heated to reflux from 1500; oil bath approx. 130 ° C. Yellowish heterogenous solution.

29/01/14. 0800, clear mixture homogenous and orange. Allowed to cool. Basified to pH 11-13 using solid KOH (about 4 g). Extracted with dichloromethane (2 × 100 mL) and ethyl acetate (100 mL). Combined organic fractions were dried with Na2SO4, concetrated under reduced pressure and dried in vacuo to give an orange solid (1.49 g, 87%)

HNMR consistent with the expected product. No purification required.

Raw HNMR KAB119-1 300 MHz CDCl3
HNMR KAB119-1 300 MHz CDCl3


--------------------------------------------
Linked Entries
]]>2014-01-28T22:28:32+00:002015-05-26T08:42:43+01:009https://www.ourexperiment.org/data/5301.xmlhttps://www.ourexperiment.org/data/5317.xmlhttps://www.ourexperiment.org/data/5319.xmlhttps://www.ourexperiment.org/data/5321.xmlhttp://www.ourexperiment.org/uri/2c4https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.htmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.htmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xmlhttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.pnghttps://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6889https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6894https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6895https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6896https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6897https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6906https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6924https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6925https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6926https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=6927https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=7055https://www.ourexperiment.org/racres_pzq/6889/Hydrolysis_of_KAB817_to_give_KAB1191.xml?revision=-1